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HOBt and HOAt-derived immonium salts: new and highly ...

Skip to main contentSkip to article Access through your organization Purchase PDF Patient Access Author links open overlay panel, Abstract Novel HOBt- and HOAt-derived immonium type coupling reagents BDMP, BPMP and AOMP were shown to be very efficient for pept

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Abstract

Novel HOBt- and HOAt-derived immonium type coupling reagents BDMP, BPMP and AOMP were shown to be very efficient for peptide synthesis with high reactivity, low racemization and good yields. X-Ray analysis indicates BOMI exists as the N-substituted form rather than as the O-substituted form assigned previously. A mechanism for amide bond formation mediated by these reagents was proposed and studied.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (9772045).

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